Well defined difluorogold( iii ) complexes supported by N-ligands

Al Bayer, Mohammad; Corbo, Robert; Dutton, Jason

doi:10.26181/608b7ec795f2c

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Well defined difluorogold( iii ) complexes supported by N-ligands

journal contribution

posted on 2021-05-17, 00:31 authored by Mohammad Al BayerMohammad Al Bayer, Robert Corbo, Jason DuttonJason Dutton

Stable difluorogold(iii) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(i) precursors using XeF or from tricationic Au(iii) precursors by displacement of the N-ligands using fluoride from economical KF. X-ray crystallographic studies of the bisimidazole ligated derivative shows the shortest Au-F bond known in a gold complex. 2

History

Publication Date

2018-01-01

Journal

Chemical Communications

Volume

54

Issue

50

Pagination

(p. 6832-6834)

Publisher

Royal Society of Chemistry (RSC)

ISSN

1359-7345

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