Well defined difluorogold( iii ) complexes supported by N-ligands

Al Bayer, Mohammad; Corbo, Robert; Dutton, Jason

doi:10.26181/608b7ec795f2c

Well defined difluorogold(III) complexes supported by N-ligands.pdf (196.31 kB)

Well defined difluorogold( iii ) complexes supported by N-ligands

journal contribution

posted on 2021-05-17, 00:31 authored by Mohammad Al BayerMohammad Al Bayer, Robert Corbo, Jason DuttonJason Dutton

Stable difluorogold(iii) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(i) precursors using XeF or from tricationic Au(iii) precursors by displacement of the N-ligands using fluoride from economical KF. X-ray crystallographic studies of the bisimidazole ligated derivative shows the shortest Au-F bond known in a gold complex. 2

History

Publication Date

2018-01-01

Journal

Chemical Communications

Volume

54

Issue

50

Pagination

(p. 6832-6834)

Publisher

Royal Society of Chemistry (RSC)

ISSN

1359-7345

Rights Statement

The Author reserves all moral rights over the deposited text and must be credited if any re-use occurs. Documents deposited in OPAL are the Open Access versions of outputs published elsewhere. Changes resulting from the publishing process may therefore not be reflected in this document. The final published version may be obtained via the publisher’s DOI. Please note that additional copyright and access restrictions may apply to the published version.