Well defined difluorogold(III) complexes supported by N-ligands.pdf (196.31 kB)
Well defined difluorogold( iii ) complexes supported by N-ligands
journal contribution
posted on 2021-05-17, 00:31 authored by Mohammad Al BayerMohammad Al Bayer, Robert Corbo, Jason DuttonJason DuttonStable difluorogold(iii) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(i) precursors using XeF or from tricationic Au(iii) precursors by displacement of the N-ligands using fluoride from economical KF. X-ray crystallographic studies of the bisimidazole ligated derivative shows the shortest Au-F bond known in a gold complex. 2