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Well defined difluorogold(III) complexes supported by N-ligands.pdf (196.31 kB)

Well defined difluorogold( iii ) complexes supported by N-ligands

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journal contribution
posted on 17.05.2021, 00:31 by Mohammad Al Bayer, Robert Corbo, Jason Dutton
Stable difluorogold(iii) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(i) precursors using XeF or from tricationic Au(iii) precursors by displacement of the N-ligands using fluoride from economical KF. X-ray crystallographic studies of the bisimidazole ligated derivative shows the shortest Au-F bond known in a gold complex. 2

History

Publication Date

01/01/2018

Journal

Chemical Communications

Volume

54

Issue

50

Pagination

(p. 6832-6834)

Publisher

Royal Society of Chemistry (RSC)

ISSN

1359-7345

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