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Weiss’ Reagents: A synthetically useful class of iodine(III) coordination compounds

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journal contribution
posted on 21.04.2021, 06:38 by Robert Corbo, Jason DuttonJason Dutton
The growing use of pyridine stabilized polycationic I(III) regents ([PhI(Pyr) ] ) as versatile oxidizing agents is reviewed. Currently the number of examples describing the use of these oxidants is modest, however those that do exist are spread across a diverse range of topic areas. The highly oxidizing nature of the [PhI(Pyr) ] polycations coupled with the potential for neutral ligand delivery to metal centers or in situ generation of the reactive [PhI] electrophile gives access to a range of novel transformations across topic areas including organic, heavy main-group centered and organometallic chemistry. 2 2 2+ 2+ +

History

Publication Date

01/01/2017

Journal

Coordination Chemistry Reviews

Volume

375

Pagination

11p.

Publisher

Elsevier

ISSN

0010-8545

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