La Trobe
Synthesis of cationic gold(III) complexes using iodine(III)_manuscript.pdf (708.91 kB)

Synthesis of cationic gold(III) complexes using iodine(III)

Download (708.91 kB)
journal contribution
posted on 30.04.2021, 02:17 by Mohammad Al Bayer, Jason Dutton
We report the synthesis and characterization of cationic Au(III) complexes supported by nitrogen-based ligands. The syntheses are achieved by reacting Au(I) complexes [Au(N-Me-imidazole) ] and [Au(pyridine)(NHC)] with iodine(III) reagents PhI(OTf)(OAc) and [PhI(pyridine) ] yielding a series of cationic gold(III) complexes. In contrast, reactions of phosphine ligated gold(I) complexes with iodine(III) reagents results in the oxidation of the phosphine ligand.

Funding

We thank La Trobe University and the Australian Research Council (JLD; FT16010007) for their generous funding of this work.

History

Publication Date

01/01/2019

Journal

Journal of Coordination Chemistry

Volume

72

Issue

8

Pagination

15p. (p. 1307-1321)

Publisher

Taylor & Francis

ISSN

0095-8972

Rights Statement

The Author reserves all moral rights over the deposited text and must be credited if any re-use occurs. Documents deposited in OPAL are the Open Access versions of outputs published elsewhere. Changes resulting from the publishing process may therefore not be reflected in this document. The final published version may be obtained via the publisher’s DOI. Please note that additional copyright and access restrictions may apply to the published version.

Exports