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Soluble, crystalline, and thermally stable alkali CO2− and carbonite (CO22−) clusters supported by cyclic(alkyl)(amino) carbenes

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journal contribution
posted on 30.03.2021, 00:56 by Lucas A Freeman, Akachukwu D Obi, Haleigh R Machost, Andrew MolinoAndrew Molino, Asa W Nichols, Diane A Dickie, David WilsonDavid Wilson, Charles W Machan, Robert J Gilliard

The direct chemical reduction of CAACCO2 adducts by alkali metals to yield multinuclear clusters is reported. The mono- and dianions of CO2 have been studied for decades and are fundamentally important oxycarbanions and critical species in CO2 fixation chemistry.

History

Journal

Chemical Science

Volume

12

Issue

10

Pagination

(p. 3544-3550)

Publisher

Royal Society of Chemistry (RSC)

ISSN

2041-6520

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