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Ring expansion of a ring expanded carbene

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posted on 2021-04-30, 05:21 authored by L García, Khalidah Hamel Mnati Al - FuraijiKhalidah Hamel Mnati Al - Furaiji, David WilsonDavid Wilson, Jason DuttonJason Dutton, MS Hill, MF Mahon
Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.

History

Publication Date

2017-01-01

Journal

Dalton Transactions

Volume

46

Issue

36

Pagination

4p. (p. 12015-12018)

Publisher

Royal Society of Chemistry

ISSN

1477-9226

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    Keywords

    Science & TechnologyPhysical SciencesChemistry, Inorganic & NuclearChemistryN-HETEROCYCLIC CARBENESROOM-TEMPERATUREBOND ACTIVATIONB-HREACTIVITYSTABILITYCOMPLEXESCATALYSISINSERTIONREAGENTSInorganic & Nuclear Chemistry

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