La Trobe

Kinetic study on the activation of PhICl2 with Lewis bases for aromatic chlorination

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posted on 2025-02-04, 00:40 authored by Benjamin DavisBenjamin Davis, Tania TaniaTania Tania, Jason DuttonJason Dutton

A study on the kinetics of the activation of PhICl2 using catalytic chloride or pyridine in electrophilic chlorination of arenes has been carried out. The results indicate that both catalysts induce the release of Cl2 from PhICl2 and that the Cl2 is the active reagent for chlorination in these reactions.

Funding

La Trobe University and the Australian Research Council (FT16010007, DP200100013).

History

Publication Date

2022-08-28

Journal

Dalton Transactions

Volume

51

Issue

32

Pagination

12384-12388

Publisher

The Royal Society of Chemistry

ISSN

1477-9226

Rights Statement

© The Royal Society of Chemistry 2022. This is the Accepted Version.

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    Keywords

    kineticsLewis baseschlorinationarenescatalystsreagent

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    In Copyright

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