Effect of Temperature and Water Salinity on Electrical Surface Conduction of Clay Particles

In this study, the combined effect of temperature (T) and pore water salinity on electrical surface conduction parameters was investigated. Two new electrical surface conduction parameters, namely, electrical conductivity of effective solid (σs) and size of diffuse double layer (DDL) water per unit volume of soil (χ), were considered in this study. The tested samples included two commercially available clays and four natural clay soils with diverse physico-chemical properties. The two surface conduction parameters were also used to assess the influence of temperature (T) and pore water salinity, as well as the electrical conductivity of free water (σFW), on the evolution of the free swelling index (FSI) of clays/clay soils through experimental methods. The findings suggested that elevated temperature and σFW increased σs but reduced χ, as well as the FSI of clays/clay soils. Furthermore, the rate of reduction for both χ and FSI augmented under the influence of increased free water salinity, particularly for clays/clay soils with high swelling capacity. The combined reductions of χ and FSI provided substantial evidence that clay DDL thickness decreases as T and σFW increase concurrently.