We report the preparation of a silicon terminated (111) diamond surface. Low energy electron diffraction and core level photoemission demonstrate that this surface is highly ordered and homogeneous and possesses a negative electron affinity. Our analysis suggests that the surface reconstruction begins with the formation of silicon trimers that coalesce into a rhombohedral 2D silicon layer reminiscent of rhombohedral silicene.
Funding
Surface doping of diamond: A new platform for 2D carbon-based spintronics
This work was supported by the Research Council of Norway through its Centres of Excellence funding scheme, Project No. 262633, "QuSpin", and the Fripro program, Project No. 250985 "FunTopoMat".