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Borataalkene Hydrofunctionalization Reactions

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posted on 2025-02-04, 03:57 authored by Tyler A. Bartholome, Jesse J. Martinez, Aishvaryadeep KaurAishvaryadeep Kaur, David WilsonDavid Wilson, Jason DuttonJason Dutton, Caleb Martin
The hydrofunctionalization of alkenes is a foundational class of reactions; however, the analogous reactions for B═C bond-containing species have been virtually unexplored. This work unearths a range of B═C hydrofunctionalization reactions with the 9-borataphenanthrene anion, including hydroalkylation, hydroarylation, hydroalkynylation, hydroamination, hydroalkoxylation, and hydration. The unique reactivity represents an addition to the synthetic chemist's toolbox to access functionalized tetracoordinate borates.

Funding

Welch Foundation (Grant No. AA-1846), the National Science Foundation for a CAREER Award (Award No. 1753025), and the ARC (FT17010007 and DP200100013).

History

Publication Date

2021-06-28

Journal

Organometallics

Volume

40

Issue

12

Pagination

1966-1973

Publisher

American Chemical Society

ISSN

0276-7333

Rights Statement

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, © 2021 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.1c00261

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