La Trobe

An extremely electron poor Au(III) trication bearing acetonitrile ligands

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posted on 2025-12-16, 05:28 authored by Lachlan BarwiseLachlan Barwise, Lachlan Moon, Bibidh Dhakal, Conor HoganConor Hogan, Keith WhiteKeith White, Jason DuttonJason Dutton
The synthesis and structural characterization of an electron poor Au(iii) trication bearing 2 imidazole and 2 acetonitrile ligands is described. The new complex is capable of aryl C-H metalation with the formation of a monomesitylene complex and also demonstrated to be highly oxidizing in the rapid room temperature conversion of cyclohexene to benzene.<p></p>

Funding

The Australian Research Council (DP200100013) and La Trobe University.

History

Publication Date

2024-05-28

Journal

Chemical Communications

Volume

60

Issue

43

Pagination

4p. (p. 5586-5589)

Publisher

The Royal Society of Chemistry

ISSN

1359-7345

Rights Statement

© The Royal Society of Chemistry 2024. This is the Accepted Version.

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